Question 12.36 In the organic compound CH2=CH–CH2–CH2–C≡CH, the pair of hydridised orbitals involved in the formation of: C2 – C3 bond is:
(a) sp – sp2(b) sp – sp3(c) sp2 – sp3 (d) sp3– sp3
Class XI Organic Chemistry : Some Basic Principles and Techniques Page 364
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HiHere is your answer,
(c) When double and triple bonds are present at equivalent bonds are present at equivalent positions, then preference is given to double bond while numbering the carbon chain. Thus,
1 2 3 4 5 6
CH₂ -- CH - CH₂ - CH₂ - C ≡ CH (-- double bond)
sp² sp² sp³ sp³ sp sp
∴ C₂ - C₃ bond if formed by overlap of sp² and sp³ orbitals.
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