Explanation:

Here's a simple Java program to display the multiplication values of the first ten natural numbers:

```java

public class MultiplicationTable {

public static void main(String[] args) {

System.out.println("Multiplication Table of the First Ten Natural Numbers:");

for (int i = 1; i <= 10; i++) {

for (int j = 1; j <= 10; j++) {

int product = i * j;

System.out.printf("%2d * %2d = %2d ", i, j, product);

}

System.out.println();

}

}

}

```

This program uses nested loops to generate the multiplication table of the first ten natural numbers. It will display the product of all possible pairs of numbers from 1 to 10.