The big difference happens later, as Port wines age in barrels or vats, depending on the style we want to create, and Madeira wine undergoes a heating process, either by stewing or “canteiro”, a process that will bring to the wine very distinct aromas, and a very different style of wine.
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Madeira is a fortified wine. It's made with red or white grapes, but mostly red grapes.
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Answer:
The big difference happens later, as Port wines age in barrels or vats, depending on the style we want to create, and Madeira wine undergoes a heating process, either by stewing or “canteiro”, a process that will bring to the wine very distinct aromas, and a very different style of wine.