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Atomization is the process of separation of all constituent atoms of a compound in the gaseous state. The process is endothermic as it involves breaking of the bonds thus the energy is required. This energy change is called 'Enthalpy of atomization.' Enthalpy of atomization is always positive.

It is referred as 'standard enthalpy of atomization' when measured for 1 mol of substances at standard conditions of [tex]\sf\:298.15 \: K[/tex]temperature and pressure of 1 bar.

E.g. for diatomic molecules, enthalpy of atomization is equal to the enthalpy of bond dissociation.

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Enthalpy of atomization, ΔaH0, is the change in enthalpy when one mole of bonds is completely broken to obtain atoms in the gas phase. For example: atomization of methane molecule.

example: atomization of methane molecule. For diatomic molecules, the enthalpy of atomization is equal to the enthalpy of bond dissociation.

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