No, not all algebraic expressions are polynomials. But all polynomials are algebraic expressions. The difference is polynomials include only variables and coefficients with mathematical operations(+, -, ×) but algebraic expressions include irrational numbers in the powers as well.
All the exponents in the algebraic expression must be non-negative integers in order for the algebraic expression to be a polynomial. As a general rule of thumb if an algebraic expression has a radical in it then it isn't a polynomial.
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